Energy generated from solar, and wind renewable sources are surging forward as contributors to achieving Net Zero. Hydrogen can be used as an energy carrier to store energy from renewable sources over a period (days to months) without generating any loss or pollution. It has been emerging as one of the leading options for future energy systems. However, the low volumetric density of hydrogen as well as the safety and economic issues associated with hydrogen storage inhibit its use as an economically viable energy vector. Among the existing routes, storage of hydrogen in the solid state as metal hydrides appears to be an attractive alternative both from the safety and the volumetric energy density points of view. It also offers high gravimetric capacity which potentially allows for storing enough hydrogen for distributed hydrogen demand. However, there are some issues with metal hydrides: (1) The rates of hydrogen absorption and desorption are strongly controlled by heat and mass transfer; the thermodynamics and kinetics limits of these hydrides cause slow hydrogenation and dehydrogenation rates. (2) The production cost of the solid hydrogen storage materials is still a major barrier to disabling scale-up for mobile or stationary applications. Metal alloys based on transition metals and rare earth elements are mostly studied, however, these significantly increase the material's cost. Lanthanum (La) has been widely used to alloy with other metals, but its price is approx. £300/kg. (3) The lightweight, excellent heat resistivity and good recyclability, as well as abundant availability and low price make Mg Hydride a good candidate (the price of Mg is approx. £3/kg). However, the excessively strong chemical bonds result in the difficulty of releasing hydrogen, typically requiring high temperatures of 300-350oC to overcome the thermodynamic energy and kinetics barriers. Addressing industry demand, key developments to cope with the above challenges will include improved energy efficiency and reduced production cost using low-cost and feasible chemical engineering solutions. Standard hydrogen sorbent modules will be developed using waste alloys and novel thermochemical energy storage (TES) which could suit multi-scale applications, particularly the heavy industry which has been widely recognised as a hard-to-decarbonize sector. It includes novelties in both hydrogen sorbent manufacturing using a 'template' method, emerging TES and induction heating, to synergistically improve the system efficiency and accelerate the dehydrogenation process, as well as the synergistic module. The success of this project will also contribute to the operating cost reduction of the solid hydrogen system and benefit researchers and engineers to accelerate hydrogen storage technology using abundant resources and low-cost technology.

Hydrogen and alternative liquid fuels (HALF) have an essential role in the net-zero transition by providing connectivity and flexibility across the energy system. Despite advancements in the field of hydrogen research both in the physical sciences and engineering, significant barriers remain to the scalable adoption of hydrogen and alternative liquid fuel technologies, and energy services, into the UK's local and national whole system infrastructure. These are technical barriers, organisational barriers, regulatory and societal barriers, and financial barriers. There are, therefore, significant gaps between current levels of hydrogen production, transportation, storage, conversion, and usage, and the estimated requirement for achieving net-zero by 2050. To address this, our proposed research programme has four interlinked work packages. WP1 will develop forward-thinking HALF technology roadmaps. We will assess supply chain availability and security. Selected representative HALF use cases will be used to identify and quantify any opportunities, risks and dependencies within a whole systems analysis. We will also develop an overarching roadmap for HALF system integration in order to inform technology advancement, industry and business development, as well as policy making and social interventions. WP2 will improve HALF characterisation and explore urgent new perspectives on the energy transition, including those related to ensuring resilience and security while also achieving net-zero. We will contrast the energy transition delivered by real incentives/behaviour versus those projected by widely-used optimisation models. The WP provides the whole systems modelling engine of the HI-ACT Hub, with a diverse array of state-of-the-art tools to explore HALF integration. WP 3 will explore the vital coupling of data and information relating to whole system planning and operational decision support, through the creation of a cyber physical architecture (CPA). This will generate new learning on current and future opportunities and risks, from a data and information perspective, which will lead to a whole system ontology for accelerated integration of hydrogen technologies. WP 4 considers options for a future energy system with HALF from a number of perspectives. The first is to consider expert views on HALF energy futures, and the public perceptions of those views. The second perspective considers place-based options for social benefit in HALF energy futures. The third perspective is to consider regulatory and policy options which would better enable HALF futures. Embedded across the research programme is the intent to create robust tools which are investment-oriented in their analysis. A Whole Systems and Energy Systems Integration approach is needed here, in order to better understand the interconnected and interdependent nature of complex energy systems from a technical, social, environmental and economic perspective. The Hub is led by Prof Sara Walker, Director of the EPSRC National Centre for Energy Systems Integration, supported by a team of 16 academics at a range of career stages. The team have extensive experience of large energy research projects and strong networks of stakeholders across England, Wales, Scotland and Northern Ireland. They bring to the Hub major hydrogen demonstrators through support from partners involved in InTEGReL in Gateshead, ReFLEX in Orkney, and FLEXIS Demonstration in South Wales for example. We shall engage to create a vibrant, diverse, and open community that has a deeper understanding of whole systems approaches and the role of hydrogen and alternative liquid fuels within that. We shall do so in a way which embeds Equality, Diversity and Inclusion in the approach. We shall do so in a way which is a hybrid of virtual and in-person field work consultation and develop appropriate digital tools for engagement.

Hydrogen and alternative liquid fuels (HALF) have an essential role in the net-zero transition by providing connectivity and flexibility across the energy system. Despite advancements in the field of hydrogen research both in the physical sciences and engineering, significant barriers remain to the scalable adoption of hydrogen and alternative liquid fuel technologies, and energy services, into the UK's local and national whole system infrastructure. These are technical barriers, organisational barriers, regulatory and societal barriers, and financial barriers. There are, therefore, significant gaps between current levels of hydrogen production, transportation, storage, conversion, and usage, and the estimated requirement for achieving net-zero by 2050. To address this, our proposed research programme has four interlinked work packages. WP1 will develop forward-thinking HALF technology roadmaps. We will assess supply chain availability and security. Selected representative HALF use cases will be used to identify and quantify any opportunities, risks and dependencies within a whole systems analysis. We will also develop an overarching roadmap for HALF system integration in order to inform technology advancement, industry and business development, as well as policy making and social interventions. WP2 will improve HALF characterisation and explore urgent new perspectives on the energy transition, including those related to ensuring resilience and security while also achieving net-zero. We will contrast the energy transition delivered by real incentives/behaviour versus those projected by widely-used optimisation models. The WP provides the whole systems modelling engine of the HI-ACT Hub, with a diverse array of state-of-the-art tools to explore HALF integration. WP 3 will explore the vital coupling of data and information relating to whole system planning and operational decision support, through the creation of a cyber physical architecture (CPA). This will generate new learning on current and future opportunities and risks, from a data and information perspective, which will lead to a whole system ontology for accelerated integration of hydrogen technologies. WP 4 considers options for a future energy system with HALF from a number of perspectives. The first is to consider expert views on HALF energy futures, and the public perceptions of those views. The second perspective considers place-based options for social benefit in HALF energy futures. The third perspective is to consider regulatory and policy options which would better enable HALF futures. Embedded across the research programme is the intent to create robust tools which are investment-oriented in their analysis. A Whole Systems and Energy Systems Integration approach is needed here, in order to better understand the interconnected and interdependent nature of complex energy systems from a technical, social, environmental and economic perspective. The Hub is led by Prof Sara Walker, Director of the EPSRC National Centre for Energy Systems Integration, supported by a team of 16 academics at a range of career stages. The team have extensive experience of large energy research projects and strong networks of stakeholders across England, Wales, Scotland and Northern Ireland. They bring to the Hub major hydrogen demonstrators through support from partners involved in InTEGReL in Gateshead, ReFLEX in Orkney, and FLEXIS Demonstration in South Wales for example. We shall engage to create a vibrant, diverse, and open community that has a deeper understanding of whole systems approaches and the role of hydrogen and alternative liquid fuels within that. We shall do so in a way which embeds Equality, Diversity and Inclusion in the approach. We shall do so in a way which is a hybrid of virtual and in-person field work consultation and develop appropriate digital tools for engagement.