Plate tectonics is the most important discovery in Earth Science and is a unique characteristic of our planet. It involves formation of new tectonic plates by seafloor spreading and their recycling back into the deep Earth at subduction zones. This process continuously repaves two-thirds of the Earth's surface. The formation of new oceanic crust represents the largest magmatic system on Earth, and involves the cooling and solidification of magma (supplied from below by partial melting of the Earth's mantle) along the 70,000 km global network of seafloor spreading axes. Understanding the details of how ocean crust forms is therefore critical to understanding the exchange of heat and mass from the solid Earth to the oceans and atmosphere. Since the rocks of the deep oceans are largely inaccessible, scientists trying to understand how magma builds new crust at spreading axes employ geophysical (seismic) experiments to investigate the sub-seafloor. Results are then compared to and combined with observations made on oceanic rocks in ophiolites (fragments of oceanic crust and upper mantle that have been pushed onto the continents and exposed above sea-level) to develop scientific models of seafloor spreading. In the search for magma chambers along the East Pacific Rise (EPR), the most magmatically active spreading axis on Earth, geophysicists have discovered thin (10's m thick) lens-shaped magma chambers (known as 'axial melt lenses') at the top of the lower crust that extend along the EPR. These are thought to sit on top of mushes made up of crystals surrounded by small amounts of magma, that feed melt upwards into the overlying melt lens. More detailed experiments have shown that the physical properties of these melt lenses change along the EPR axis, suggesting that the proportion of melt to mush along the EPR varies on a range of length-scales. Upwards expulsion of magma from the melt lens happens periodically via forceful intrusion of sheets of magma (forming so-called "sheeted dyke complexes"), leading to eruption of lava on to the seafloor. This geophysical picture of the magmatic plumbing system of seafloor spreading axes (based mostly on decades-old inferences from seismic experiments) is incomplete, however, and lacks any constraints on the pathways followed by magma migrating into and out of axial melt lens systems. Lateral variations in seafloor morphology and erupted lava compositions suggest that there must be significant along-axis (3D) transport and evolution of melt, but how extensively this occurs, at what level(s) within the crust, and by what mechanisms remain unknown. These questions have broad implications for the overall process of melt generation and delivery from the mantle and formation of ocean crust, and can only be answered by quantifying melt transport trajectories along a spreading axis in detail and by combining this with determinations of magma geochemistry. This project addresses these questions by directly determining the migration pathways followed by magma as it enters and exits from an axial melt lens system that has been mapped out along a 100 km complete spreading segment preserved in the Oman ophiolite. This provides the world's only on-land analog for fast-spreading axes like the EPR. We will use a technique called 'anisotropy of magnetic susceptibility' or 'AMS' to measure the 3D preferred alignments of crystals resulting from the flow of magma during the formation of crustal rocks. We will then combine these observations with geochemical analyses of rock compositions to establish whether and how 3D spatial variations in magma flow regimes along a fast-spreading axis control the geochemical evolution of magmas during crustal construction. This novel approach will allow us to develop a comprehensive model for the anatomy of the magma systems responsible for forming two-thirds of the Earth's surface, testing and challenging the predictions of remotely-sensed seismic investigations.

Monsoon systems influence the water supply and livelihoods of over half of the world. Observations are too short to provide estimates of monsoon variability on the multi-year timescale relevant to the future or to identify the causes of change on this timescale. The credibility of future projections of monsoon behavior is limited by the large spread in the simulated magnitude of precipitation changes. Past climates provide an opportunity to overcome these problems. This project will use annually-resolved palaeoenvironmental records of climate variability over the past 6000 years from corals, molluscs, speleothems and tree rings, together with global climate-model simulations and high-resolution simulations of the Indian, African, East Asia and South American monsoons, to provide a better understanding of monsoon dynamics and interannual to multidecadal variability (IM). We will use the millennium before the pre-industrial era (850-1850 CE) as the reference climate and compare this with simulations of the mid- Holocene (MH, 6000 years ago) and transient simulations from 6000 year ago to ca 850 CE. We will provide a quantitative and comprehensive assessment of what aspects of monsoon variability are adequately represented by current models, using environmental modelling to simulate the observations. By linking modelling of past climates and future projections, we will assess the credibility of these projections and the likelihood of extreme events at decadal time scales. The project is organized around four themes: (1) the impact of external forcing and extratropical climates on intertropical convergence and the hydrological cycle in the tropics; (2) characterization of IM variability to determine the extent to which the stochastic component is modulated by external forcing or changes in mean climate; (3) the influence of local (vegetation, dust) and remote factors on the duration, intensity and pattern of the Indian, African and South American monsoons; and (4) the identification of palaeo-constraints that can be used to assess the reliability of future monsoon evolution.

Hexagonal boron nitride (hBN) is currently attracting international attention due to its technological potential for deep ultraviolet (UV) photonics, single photon emission and its incorporation into van der Waals (vdW) heterostructures. hBN is a layered material in which strong covalent bonds between boron and nitrogen atoms stabilise a planar honeycomb atomic arrangement. In its bulk form hBN consists of many such planes stacked on top of each other, and, like graphite, layers of hBN with thickness down to a single monolayer can be exfoliated from bulk crystals. There have been many demonstrations showing that exfoliated hBN layers can be combined with other layered materials, for example graphene, to form 'van der Waals heterostructures' in which hBN acts as a tunnel barrier, substrate or gate dielectric. The interest in hBN has motivated many groups to explore the growth of thin films and monolayers of hBN using various techniques, but it has proved difficult to reproduce the optical and electrical properties of the highest-quality mm-scale bulk hBN crystals, which are grown by our Project Partners in Tsukuba (Japan). In a recent breakthrough, we demonstrated that hBN can be grown using high-temperature molecular beam epitaxy (HT-MBE) and that layers grown using this technique have unprecedented optical quality with strong luminescence in the deep UV region with a photon energy, for monolayer thickness, of 6.08 eV. This high photon energy offers the prospect of solid-state devices emitting light in the UV-C range, which is known to be relevant to water purification and surface sterilisation. In collaboration with Australian academics, we have also shown that single photon emitters can be formed in our hBN material. In addition, we have demonstrated the growth of lateral heterostructures of graphene and boron nitride, in which the composition varies within a single monolayer. These structures are predicted to have novel electronic and magnetic properties. In order to build on our promising early results and realise the technological potential of hBN, we now propose to advance our understanding of the relevant growth mechanisms and explore, both in Nottingham and through our network of international collaborations, the technological opportunities provided by high quality hBN monolayers and thin films. Our hypothesis is that HT-MBE provides a route to the scalable growth of high-quality hBN layers, which have the potential for technological exploitation in the areas of deep UV photonics, single photon sources and vdW heterostructures, as well as the exploration of the electronic properties of hBN edge states and lateral heterojunctions. In our research programme we will investigate and optimise HT-MBE growth of hBN. In addition, we will explore doping of hBN and the formation of simple optoelectronic devices, as well as the growth of hBN-based alloys of BNC and BNSi as a route to the spontaneous formation of phase separated nanostructures and band gap engineering. In addition, we will establish the relationship between growth parameters and the formation of carbon-induced single photon emitters in hBN. To determine the potential of HT-MBE-grown hBN for deep UV photonics, we will fabricate prototype devices operating at UV-C wavelengths. We will also utilise epitaxial hBN to study the formation and structure of lateral hBN/graphene heterojunctions and investigate the emergence of novel electronic and magnetic effects in these structures due to electron-electron interactions. An important further objective is to demonstrate the scalable growth of hBN on large area substrates, which are commercially available, for example sapphire and silicon carbide, so that the hBN layers are compatible with processing and fabrication techniques, which are used widely in industry.

The origin of new biological species depends on the evolution of characters that prevent them from mating and producing successful offspring. This evolutionary process may start with adaptation to new environments but this rarely creates a complete reproductive barrier. If some interbreeding occurs, then genes which are not directly involved in adaptation to different habitats can still be shared. We still have little understanding of how evolution proceeds from this point to the point of complete prevention of interbreeding. In this project, we propose to study the pea aphid because its genome has been sequenced and it is known to feed on several different host plant, which represent distinct environments. We know that aphids tend to reproduce with others that use the same plant. This tendency is stronger in some cases than others so we have several points on the progression towards new species that we can compare. Aphids use chemical cues to choose the plant on which they feed and we now know the types of genes underlying recognition of these cues. We have already found some of these genes that are likely to be involved in the differences in behaviour between aphids that use different plants. In this new project we want to find out how these genes are influenced by natural selection and how they affect the sharing of other genes between host races of aphids. We also want to find out which chemicals in the plants are used in the recognition process. This will help us to understand the origin of species and it may also help in control of aphids that are pests of crops. Understanding how aphids choose the plants they want to feed on can provide new tools to prevent aphid damage.

We have known for the last 50 years that Europe and America have been moving apart at about 2cm/yr by processes of seafloor spreading that generate new oceanic crust at the submarine mid-Atlantic Ridge. This is one of the fundamental processes of Plate Tectonics, and has shaped the planet that we live on. Yet because we cannot use standard remote sensing techniques using electromagnetic radiation to study the seafloor, in many ways we know more about the surface of Mars than we do about the floor of the Atlantic! Over the last 12 years improved sonar surveys of the mid Atlantic Ridge have revealed a new mode of seafloor spreading where a significant part of the plate divergence is taken up by slip on long-lived, convex upward detachment faults, rather than mainly by magmatic intrusion. Up to half of the Atlantic seafloor may have formed in this way. These detachment faults are associated with large hydrothermal systems producing black smokers venting 400 C fluids on the seafloor. On fast (10-15 cm/yr) spreading ridges such as the East Pacific Rise, black smoker systems are small, short-lived, and located in zones of active volcanism, and are supplied with heat by shallow (1-2 km) magma chambers that are there more or less all the time. These systems have been modelled extensively, and a key element is the existence of a thin conductive boundary layer between molten magma and the hydrothermal fluid. On the mid-Atlantic ridge, black smoker systems are more widely spaced, larger, and longer lived, and often are located a few km away from the zone of active volcanism. These systems may in some cases be controlled by fluid flow up detachment faults, with heat supplied by episodic magma chambers as deep as 7km below seafloor, and much less numerical modelling work has been done on them. We have identified a fossil thermal boundary layer in a detachment fault sampled by drilling. In this proposal we plan to investigate this boundary layer more thoroughly, as well as the complex interrelationships between faulting, magmatism and hydrothermal circulation at slow spreading ridges. We will address this problem by building thermal and hydrothermal numerical models to predict both the asymmetric thermal structure produced by detachment faulting and the hydrothermal circulation patterns associated with permeable fault zones and localised magmatism. The hydrothermal models have to be very sophisticated because of the complicated properties of water, which changes density and viscosity very rapidly in the temperature range of black smoker systems. Hence we will work with experienced modellers in Paris to achieve our aims. We will test these models using data on cooling rates of rocks from IODP core in the footwall of an exposed detachment fault in the Atlantic - these cooling rates are calculated by comparing the compositions of natural minerals with experimental data on diffusion rates of trace elements. The aim of our models is not to replicate nature precisely (there are too many unknowns to do that) - but to test the range of parameter values that generate acceptable results. For example, the model must generate vents with the temperature measured on the seafloor and the heat output estimated from geochemical data - what are the minimum values of fault zone thickness and permeability that allow this to happen? These values can then be compared with physical models of permeability based on fracture densities and seismicity distributions. Because it is hard to observe subsurface geology or fluid flow directly, modelling is often the only way of determining whether hypotheses are realistic. At the end of this project we will have a better understanding of one of the most important but least accessible parts of the Earth System - the formation of new lithosphere at ridge crests, and the complex interactions between the ocean and the crust that occur as a result of this process.