The purpose of the proposed research is to investigate the importance of sea-level feedbacks (SLF) in stabilizing marine-based ice sheets during their retreat. The proposed investigation will combine new late Pleistocene/Holocene relative sea-level constraints to be collected from raised shorelines, existing offshore marine cores, and isolation basins from across northwestern Scotland to refine the glacial isostatic adjustment (GIA) models for the British Isles. The proposal will also investigate SLF feedbacks at a more local level and at the scale of a Late Pleistocene ice stream that once flowed through the Minch of northwestern Scotland. Specifically, we will test three hypotheses: 1.) SLF did not provide a stabilizing influence for the Minch Ice Stream during its retreat following the Last Glacial Maximum, 2.) along indented ice-sheet margins, SLF are governed not by the local ice front but by the regional GIA signal, and 3.) the influence of SLF in stabilizing marine ice streams is a function of the rheology of the Earth beneath it. One of the largest uncertainties related to future projections of sea-level rise is the influence of ice sheets. Model projections differ by as much as 2 m over the next 100 years depending on how existing ice sheets behave with respect to ongoing sea-level rise and warming. Our understanding of the feedbacks between ice sheet behaviour and sea-level changes at the scale of extant ice streams of concern (e.g. Thwaites Glacier in Antarctica, Jakobshavn Isbrae in Greenland) is limited to numerical models that have rarely been tested against real-world examples at decadal to century time-scales. The retreat of ice streams following the Last Glacial Maximum provides an excellent test ground for the factors controlling the behaviour of ice streams during their retreat. The data generated as part of this project will not only examine ice-sheet behaviour but also contribute to GIA models used to predict future sea-level changes and past studies of climate, paleogeography, and archaeology. It will also provide some of the first absolute ages on raised shorelines across northwestern Scotland.

New manufacturing methods are required if we are to live sustainably on the earth. In the electronics industry there is enormous interest in the possibility of manufacturing devices using organic materials: they can be manufactured sustainably from earth-abundant resources at energy costs that are typically significantly less than those associated with the production of equivalent inorganic materials. Electronic devices based on organic components are now readily available in the high street. For example, organic light-emitting diodes are used to produce the displays used in some high-end TV sets and in smartphones (e.g. iPhone X). However, a fundamental problem prevents the realisation of the full potential of organic materials in electronic devices. When light is absorbed by molecular semiconductors, it causes the creation of excitons - pairs of opposite charges - that carry excitation through the device. However, the excitons in organic materials recombine and cancel themselves out extremely rapidly - they can only move short distances through the material. This fundamental obstacle limits the application of organic materials in consumer electronics and also in many other areas of technology - in quantum communications, photocatalysis and sensor technologies. We propose an entirely new approach to solving this problem that is based on combining molecular designs inspired by photosynthetic mechanisms with nanostructured materials to produce surprising and intriguing quantum optical effects that mix the properties of light and matter. On breadboards, threaded mounts hold optical components relative to one another so that rays of light can be directed through an optical system. This proposal also aims to design breadboards, but of a very different kind. The smallest components will be single chromophores (light absorbing molecules), held at fixed arrangements in space by minimal building blocks called antenna complexes, whose structures are inspired by those of proteins involved in photosynthesis. Antenna complexes are designed and made from scratch using synthetic biology and chemistry so that transfer of energy can be controlled by programming the antenna structure. Instead of using threaded mounts, we will organise these components by attachment to reactive chemical groups formed on solid surfaces by nanolithography. In these excitonic films, we will develop design rules for efficient long-range transport. In conventional breadboards, light travels in straight lines between components. However, we will use the phenomenon of strong light-matter coupling to achieve entirely different types of energy transfer. In strong coupling, a localised plasmon resonance (an light mode confined to the surface of a nanoparticle) is hybridised with molecular excitons to create new states called plexcitons that combine the properties of light and matter. We will create plexcitonic complexes, in each of which an array of as many as a thousand chromophores is strongly coupled to a plasmon mode. In these plexcitonic complexes, the coupling is collective - all the chromophores couple to the plasmon simultaneously, and so the rules of energy transfer are completely re-written. Energy is no longer transferred via a series of linear hopping steps (as it is in organic semiconductors), but is delocalised instantaneously across the entire structure - many orders of magnitude further than is possible in conventional organic semiconductors. By designing these plexcitonic complexes from scratch we aim to create entirely new properties. The resulting materials are fully programmable from the scale of single chromophores to macroscopic structures. By combining biologically-inspired design with strong light-matter coupling we will create many new kinds of functional structures, including new medical sensors, 'plexcitonic circuits', and quantum optical films suitable for many applications, using low-cost, environmentally benign methods.

We will launch a new CDT, focused on composite materials and manufacturing, to deliver the next generation of composites research and technology leaders equipped with the skills to make an impact on society. In recent times, composites have been replacing traditional materials, e.g. metals, at an unprecedented rate. Global growth in their use is expected to be rapid (5-10% annually). This growth is being driven by the need to lightweight structures for which 'lighter is better', e.g. aircraft, automotive car bodywork and wind blades; and by the benefits that composites offer to functionalise both materials and structures. The drivers for lightweighting are mainly material cost, fuel efficiency, reducing emissions contributing to climate change, but also for more purely engineering reasons such as improved operational performance and functionality. For example, the UK composites sector has contributed significantly to the Airbus A400M and A350 airframes, which exhibit markedly better performance over their metallic counterparts. Similarly, in the wind energy field, typically, over 90% of a wind turbine blade comprises composites. However, given the trend towards larger rotors, weight and stiffness have become limiting factors, necessitating a greater use of carbon fibre. Advanced composites, and the possibility that they offer to add extra functionality such as shape adaptation, are enablers for lighter, smarter blades, and cheaper more abundant energy. In the automotive sector, given the push for greener cars, the need for high speed, production line-scale, manufacturing approaches will necessitate more understanding of how different materials perform. Given these developments, the UK has invested heavily in supporting the science and technology of composite materials, for instance, through the establishment of the National Composites Centre at the University of Bristol. Further investments are now required to support the skills element of the UK provision towards the composites industry and the challenges it presents. Currently, there is a recognised skills shortage in the UK's technical workforce for composites; the shortage being particularly acute for doctoral skills (30-150/year are needed). New developments within industry, such as robotic manufacture, additive manufacture, sustainability and recycling, and digital manufacturing require training that encompasses engineering as well as the physical sciences. Our CDT will supply a highly skilled workforce and technical leadership to support the industry; specifically, the leadership to bring forth new radical thinking and the innovative mind-set required to future-proof the UK's global competitiveness. The development of future composites, competing with the present resins, fibres and functional properties, as well as alternative materials, will require doctoral students to acquire underpinning knowledge of advanced materials science and engineering, and practical experience of the ensuing composites and structures. These highly skilled doctoral students will not only need to understand technical subjects but should also be able to place acquired knowledge within the context of the modern world. Our CDT will deliver this training, providing core engineering competencies, including the experimental and theoretical elements of composites engineering and science. Core engineering modules will seek to develop the students' understanding of the performance of composite materials, and how that performance might be improved. Alongside core materials, manufacturing and computational analysis training, the CDT will deliver a transferable skills training programme, e.g. communication, leadership, and translational research skills. Collaborating with industrial partners (e.g. Rolls Royce) and world-leading international expertise (e.g. University of Limerick), we will produce an exciting integrated programme enabling our students to become future leaders.

We propose to develop and validate measures of accountability to be shared with the Nepal Ministry of Education (MOE) and to use those measures in an analysis of the determinants of accountability and its association with students' gains in achievement. The proposed study will build on the resources of the Chitwan Valley Family Study (CVFS), a 20-year ongoing panel study of 116 schools with 3,000 households with 3,500 school aged children in 151 communities located throughout the Western Chitwan Valley of Nepal. With funding from DFID-ESRC, we are proposing to achieve two aims: Aim One: To Develop and Pretest a Suite of Nepali Accountability Assessment Tools (NAATs) for Use by the MOE and to Pilot these Tools within the Chitwan Valley of Nepal. Importantly, the tools will be designed so that Nepal's MOE can both assess and potentially improve its current accountability processes at multiple levels of the increasingly decentralized Nepalese education system [4]. To achieve this aim we will: (1) develop a variety of accountability assessment tools for use in Nepal's education system; (2) modify a set of instructional processes and instructional quality measures developed for use in OECD countries for use in the Nepali educational system; and (3) gather data on students' academic achievement using standardized test items developed by Nepal's MOE. Aim Two: To Investigate How Accountability Processes; Environments for Student Learning in Schools, Families, and Communities; and Student Learning are Related. This involves investigating three main research questions: Are accountability processes systematically related to socioeconomic disparities among communities, schools within communities, and families within schools? In school and community settings where accountability processes are more intensive, is the quality of instructional service delivery higher? And, controlling for socioeconomic disparities related to student achievement is student learning higher in schools and communities where accountability processes are more intensive? To meet this aim, we will: (1) administer a newly designed PET-QSDS survey to 380 key stakeholders; (2) administer the NASA test at the beginning and end of the school year and a student survey to 1,740 8th graders; and (3) administer a teacher survey to 1,392 teachers and a parent survey to 1,740 parents. The results of this research will be relevant to education policy makers in Nepal and will also contribute directly to comparative education research on school effectiveness. This study will generate rigorous scientific outcomes: (1) development of a low income context adaptive accountability assessment tool; (2) cross-cultural assessment of the reliability and predictive validity of accountability measures; (3) identification of contextual factors with strong correlation with accountability; (4) potential for identification of new dimensions of accountability in low income settings; and (5) scientific advancement in our understanding of the relationship between accountability, instructional quality and students' gains in achievement. These outcomes will be made widely available to scientists and policy makers. First, we will conduct dissemination workshops at local and national levels to share findings of the study and provide training on the use of the newly designed accountability assessment tool and analysis of the data generated through the various surveys mentioned above. Second, the data will be made available through ICPSR and the UK Data Service. Third, the findings will be disseminated through presentations at national and international conferences and published in scientific articles, and research and policy briefs. Finally, the participation of Nepali faculty, scientists, government representatives and school authorities throughout the project will advance the scientific and analytical capacity of their respective host institutions (DOE,TU, PABSON, PDs).

In the 20th century plastics became an indispensable part of modern life. Most plastic products are produced by melting polymer materials and moulding them into different shapes. The flow or rheological behaviour of molten polymers is highly sensitive to their molecular architectures and molecular weight distributions. Presence of a small amount of long chain branching structures in commercial polymers can alter their rheological and thus processing properties significantly. Therefore a thorough understanding of the relationship between polymer branching and rheology is of crucial importance to the multi-billion pounds plastics industry. The dominant contributions in defining this relationship come from two respects: entanglement effects among long polymer chains or branches and complexity in branching architectures. The entanglement effects originate from the fact that long polymer chains can not pass through each other. As a consequence, the lateral motion of the chains are suppressed, leading to the extremely long relaxation time and characteristic viscoelastic behaviour of entangled polymers, which are qualitatively different from the viscous behaviour of fast relaxing simple liquids. Theoretical works on entanglement dynamics have been for 40 years primarily based on the tube theory. This model assumes that the motion of a linear polymer chain is restricted to a tube-like region along its contour formed by surrounding chains, similar to a snake slithering through an array of obstacles. Recent tube theories can provide appropriate description of the linear rheology of monodisperse linear polymers, but is facing serious difficulties in describing the branched polymers. Synthesized branched polymers can have various architectures, such as star, H-shaped, comb and Cayley-tree polymers. The commercial polymers, such as metallocene polyethylene resins, can even have branches on branches, i.e., hyperbranching, structures. The branching structures prevent these polymers from sliding in the melt as do the linear chains. Instead a star polymer diffuses by retracting its arms all the way to the branch point, allowing this point to move a short distance, and then stretching out the arms again. This is analogous to an octopus entangled in an array of topological constraints (e.g., a fishing net). The relaxation time of stars thus grows exponentially with the length of the arms, in radical contrast to the power law chain-length dependence of the linear polymers. Polymers with more complicated architectures are assumed to relax in a hierarchical way. The relaxation starts from the retraction of the outermost branch arms and proceeds to inner segments layer by layer till the core of the molecule. Theoretical modelling of the branched polymers needs to address several essential questions including the dynamics of the branch arm retraction, the branch point diffusion and the hierarchical relaxation, as well as the reduced entanglement effects caused by the relaxation of surrounding polymers. The fast grow in computer power and simulation techniques enables us to examine these problems in great details. In this project, we propose to perform molecular dynamics simulations to investigate the relaxation dynamics of model branched polymers at the microscopic level. Special attention will be paid to examine and, if needed, re-formulate the assumptions and analytical expressions used in the current tube theories for describing the above-mentioned dynamic processes. Based on these microscopic understanding, more coarse-grained theoretical models will be developed, which will ultimately allow prediction of dynamics and rheology of general mixtures of branched polymers with arbitrary architectures over many decades of time and length scales.